Thermodynamics studies energy
First Law of Thermodynamics: Conservation of Energy, which states that energy can't be created or destroyed. Energy can only change form. The total amount of energy is constant.
Primary Dimensions:
- Mass (m, kilogram)
- Length (L, meter)
- Time (t, seconds)
- Temperature (T, kelvin)
- Electric Current (A, ampere)
- Amount of Light (cd, candela)
- Amount of Matter (mol, mole)
Secondary Dimensions: Formed by combining primary dimensions.
- Velocity
- Energy
- Volume
- Specific Weight
- Specific Gravity
- Specific Energy
- Specific Internal Energy
- Specific Enthalpy
- Density
- etc.
Force = Mass x Acceleration
The Force needed to accelerate an object of 1 kilogram at a rate of 1 meter per second squared.
- Force: measured in Newtons(N) or Pound-Force(lbf)
Mass and weight are often confused. Weight equals mass multiplied by the gravitational acceleration (W = mg) and is a force. The gravitational acceleration (at sea level) is 9.81 meters per second squared, or in english units it's 32.2 feet per second squared.
Specific Weight (symbol is gamma): This is the weight of a unit of volume. This equals the density multiplied by the gravitational acceleration.
Work: A type of energy, with units of newton(N) multiplied by meter(m) which equals a joule (J) from the units you can see that work equals a force over a distance.
Watt (W): This is the time rate of work(energy) and has units of watts. A watt is equal to a joule per second (W = J/s). This is commonly known as power.
System: an area of study surrounded by a boundary. Three Types:
- Closed/Control Mass: Mass can't cross the boundary, so it is constant. However, energy may cross the boundary such as heat or work. The volume can change.
- Open/Control Volume: A steady flow process where mass and energy can cross the boundary, called mass flow. The volume is fixed.
- Isolated: Mass and energy can't cross the boundary.
Boundary: real/imaginary line that separates the system and surroundings.
Surroundings: anything outside of the system.
Property: a characteristic of a system. Two types:
- Intensive: independent of the mass in the system such as temperature, density, and pressure. Generally lowercase letters are used except for temperature(T) and pressure(P).
- Extensive: properties that depend on the size of the system such as mass and volume. Uppercase letters are used except for mass(m).
Specific properties: extensive properties per unit mass.
Density: mass per unit volume. Temperature and pressure can affect density.
State: condition of a system. Defined by two independent intensive properties.
Equilibrium: balanced state, no changes.
Thermal Equilibrium: constant temperature throughout the system.
Mechanical Equilibrium: constant pressure.
Phase Equilibrium: constant mass.
Chemical Equilibrium: constant chemical composition.
Quasi-Equilibrium: slow process where the system remains close to equilibrium.
Simple compressible system: no effects from electrical, magnetic, gravitational, motion, and surface tension.
Path: series of states.
Process: change between equilibrium states. Several types:
- Isothermal: constant temperature.
- Isobaric: constant pressure.
- Isochoric/Isometric: constant specific volume.
Cycle: a system returning to the initial state after the final state.
Steady: no change over time.
Uniform: no change over a region.
Zeroth Law of Thermodynamics: if two separate objects in thermal equilibrium with another object, then the original two objects are in thermal equilibrium with one another.
Temperature:
- Kelvin (K) T(K) = T(Celsius) + 273
- Rankine (R) T(R) = T(Fahrenheit) + 460 and T(R) = 1.8 T(K)
- Celsius (degree C)
- Fahrenheit (degree F) and T(Fahrenheit) = 1.8 T(Celsius) +32
Pressure: force per unit area. Units - Pascal(Pa) = one newton per meter squared.
Absolute Pressure: actual pressure.
Gauge Pressure: the difference between absolute and local atmospheric pressures, many devices read zero in the atmosphere. P
gauge = P
abs - P
atmVacuum Pressure: below atmospheric pressure. P
vac = P
atm - P
absPressure does not change horizontally when in a fluid at rest. Pressure changes with vertical distance. The pressure between two points in a constant density fluid equals density multiplied by the gravitational acceleration multiplied by the vertical distance between the two points.
P = density x gravitational acceleration x vertical distance
Standard atmospheric pressure is 760mmHg at 0 (degrees C), 760 torr, or 1 atm.
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